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981.
982.
This annual review of laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) covers the year 2003. Significant advances were made in understanding laser-sample interactions. In particular, research defined the distribution of particle sizes produced by the interplay of laser wavelength, laser pulse width and the gas environment of ablation. A link between particle sizes and elemental and isotopic fractionation at both the ablation site and in the ICP was established. Experimental 15 7 nm and femtosecond laser systems were tested with promising results. The number of applications of LA-ICP-MS in geology and environmental Earth science continued to grow with particular interest in element concentration and isotope ratio profiling of materials, linking composition to time scales. In situ isotopic ratio measurements were increasingly made using multicollector magnetic sector ICP-MS instruments. Other applications of wide interest included bulk sampling of rocks and ores prepared as lithium borate glasses; low level analysis of platinum-group elements, rhenium and gold in sulfides, metal and silicates; in situ uranium-lead zircon geochronology; and melt and fluid inclusion analysis.  相似文献   
983.
The age and tectonosedimentary environment of the Palaeozoic sediments on the Frontal Cordillera is not well known and earlier studies have been unable to satisfactorily explain the geological history of the basement of the Andes.In the vicinity of the old Castaño Viejo mine crop out various levels of partially metamorphosed microbialite limestones, which alternate with thin marly–lutitic interstrata. These levels contain abundant palynomorph remains, which allow the series to be dated as Silurian–Devonian. These data, together with the presence of warm climate fossils, lend support to the hypothesis of a major allochtony of the Chilenia Terrane (of which the Frontal Cordillera formed part), relative to the Cuyania Terrane (which included the Precordillera), prior to their amalgamation.Upper Carboniferous palynomorphs found during this study occur in association with resedimented palynomorphs and chitinozoa, of possible Devonian age. This demonstrates the equivalence of both fossiliferous series and their location within the upper part of the Upper Carboniferous Agua Negra Fm. The Silurian–Devonian elements, deformed during a phase prior to the Gondwanic orogeny, were eroded and transported to the foreland basin during the Upper Carboniferous.The palynomorph associations found in all samples correspond to the Ancistrospora palynological zone and to the Raistrickia densaConvolutispora muriornata Biozone, which are indicative of Upper Carboniferous times. Characteristic forms such as Ancistrospora verrucosa and C. muriornata, both indicative of an Upper Carboniferous age, were found in samples from the Castaño Viejo area.Earlier interpretations of the Frontal Cordillera attributing the sedimentation to a palaeo-latitude at some distance from Gondwana, were based on the presence of Silurian–Devonian hot water stromatolithic limestones. Our results suggest that Cuyania and Chilenia were not necessarily separated by a great distance before their amalgamation. This in turn means that a large ocean was not necessarily consumed in the process.  相似文献   
984.
Twenty-four new zircon and apatite fission track ages from the Getic and Danubian nappes in the South Carpathians are discussed in the light of a compilation of published fission track data. A total of 101 fission track ages indicates that the Getic nappes are generally characterized by Cretaceous zircon and apatite fission track ages, indicating cooling to near-surface temperatures of these units immediately following Late Cretaceous orogeny.The age distribution of the Danubian nappes, presently outcropping in the Danubian window below the Getic nappes, depends on the position with respect to the Cerna-Jiu fault. Eocene and Oligocene zircon and apatite central ages from the part of the Danubian core complex situated southeast of this fault monitor mid-Tertiary tectonic exhumation in the footwall of the Getic detachment, while zircon fission track data from northwest of this fault indicate that slow cooling started during the Latest Cretaceous. The change from extension (Getic detachment) to strike-slip dominated tectonics along the curved Cerna-Jiu fault allowed for further exhumation on the concave side of this strike-slip fault, while exhumation ceased on the convex side. The available fission track data consistently indicate that the change to fast cooling associated with tectonic denudation by core complex formation did not occur before Late Eocene times, i.e. long after the cessation of Late Cretaceous thrusting.Core complex formation in the Danubian window is related to a larger-scale scenario that is characterized by the NNW-directed translation, followed by a 90° clockwise rotation of the Tisza-Dacia “block” due to roll-back of the Carpathian embayment. This led to a complex pattern of strain partitioning within the Tisza-Dacia “block” adjacent to the western tip of the rigid Moesian platform. Our results suggest that the invasion of these southernmost parts of Tisza-Dacia started before the Late Eocene, i.e. significantly before the onset of Miocene-age rollback and associated extension in the Pannonian basin.  相似文献   
985.
Changes in the stress field of an aquifer system induced by seismotectonic activity may change the mixing ratio of groundwaters with different compositions in a well, leading to hydrochemical signals which in principle could be related to discrete earthquake events. Due to the complexity of the interactions and the multitude of involved factors the identification of such relationships is a difficult task. In this study we present an empiric statistical approach suitable to analyse if there is an interdependency between changes in the chemical composition of monitoring wells and the regional seismotectonic activity of a considered area. To allow a rigorous comparison with hydrochemistry the regional earthquake time series was aggregated into an univariate time series. This was realized by expressing each earthquake in form of a parameter “e”, taking into consideration both energetic (magnitude of a seismic event) and spatial parameters (position of epi/hypocentrum relative to the monitoring site). The earthquake and the hydrochemical time-series were synchronised aggregating the e-parameters into “earthquake activity” functions E, which takes into account the time of sampling relative to the earthquakes which occurred in the considered area. For the definition of the aggregation functions a variety of different “e” parameters were considered. The set of earthquake functions E was grouped by means of factor analysis to select a limited number of significant and representative earthquake functions E to be used further on in the relation analysis with the multivariate hydrochemical data set. From the hydrochemical data a restricted number of hydrochemical factors were extracted. Factor scores allow to represent and analyse the variation of the hydrochemical factors as a function of time. Finally, regression analysis was used to detect those hydrochemical factors which significantly correlate with the aggregated earthquake functions.This methodological approach was tested with a hydrochemical data set collected from a deep well monitored for two years in the seismically active Vrancea region, Romania. Three of the hydrochemical factors were found to correlate significantly with the considered earthquake activities. A screening with different time combinations revealed that correlations are strongest when the cumulative seismicity over several weeks was considered. The case study also showed that the character of the interdependency depends sometimes on the geometrical distribution of the earthquake foci. By using aggregated earthquake information it was possible to detect interrelationships which couldn't have been identified by analysing only relations between single geochemical signals and single earthquake events. Further on, the approach allows to determine the influence of different seismotectonic patterns on the hydrochemical composition of the sampled well. The method is suitable to be used as a decision instrument in assessing if a monitoring site is suitable or not to be included in a monitoring net within a complex earthquake prediction strategy.  相似文献   
986.
F. 《Earth》2005,70(3-4):167-202
Sand-rich submarine fans are radial or curved in plan view depending on the slope of the basin floor. They occur isolated or in coalescing systems. The fans' average lateral extent measures close to 25 km and their thickness usually less than 300 m. The thickness of outer fan sequences averages around 120 m and that of middle fan successions around 160 m. Rarely reported inner fan sequences have a maximum thickness of 80 m.

The formation of sand-rich fans is closely related to tectonic activity. Their sediment is coarse-grained and compositionally immature as indicated by significant feldspar content due to close provenance and rapid transport by short rivers with a steep gradient controlled by tectonism. Tectonic activity also provides for narrow shelves making the fans relatively insensitive to sealevel changes. Formation of sand-rich fans typically occurs in restricted continental basins. The tectonic settings are highly variable. Sand-rich fans typically receive their sediment through submarine canyons which intercept sand from longshore drift and/or are fed more or less directly by regional rivers.

The type of ancient fan system (radial, curved, isolated, coalescing) may be identified through paleocurrent map plots, facies map sketches, recognition of lateral thickness variations and sediment influx centers, as well as lateral bed correlations defining the minimum fan extent.

Important in distinguishing different environments of ancient fans are detailed measured sections, their comparison and correlation. Channelized inner fan and middle fan deposits may be distinguished from the unchannelized outer fan successions through bed correlation tests which reflect their different stratigraphic architectures and bedding patterns. Bedding in outer fan deposits (lobes) is relatively simple, parallel, and regular. The lateral bed continuity is relatively high. Channel fills, especially those of middle fan distributary channels, display a complicated bedding pattern with vertical and lateral random distribution of channel fills, axial erosion, and bed convergence towards the channel margins. Channel fills exhibit only linear bed continuity. Thus, the probability in carrying out local to regional scale lateral bed correlations is almost exclusively limited to outer fan deposits.

The measured sections will help further distinguish fan environments by revealing: (1) different facies associations in outer fan sequences (mainly B, C and D) and middle fan successions (mainly A, B, C, D, and channel margin facies); (2) greater average bed and layer thicknesses in middle fan as opposed to outer fan successions (“bed” and “layer” as used herein); (3) more frequent amalgamation surfaces in channel fills than in unchannelized outer fan deposits; (4) more frequent tabular amalgamation surfaces in outer fan sections; (5) more frequent nontabular amalgamation surfaces in channel fills; and (6) more frequent dish structures in middle fan than outer fan successions.

Rarely exposed fan valley fills may be identified by coarse conglomerates. Moreover, in proximity to fan valley fills, relatively mud-rich sediments may be observed that derive from the depositional system of the basin slope.  相似文献   

987.
In late-June, 1998, a series of thunderstorms dropped 16.5 cm (6.5 in.) of rain in a 72-h period over southeastern Ohio, causing extensive flooding, six deaths, and 179 million dollars in property damage. The storms also triggered more than 60 shallow landslides along a 64 km (40-mi) stretch of Interstate 77 between Buffalo and Marietta, Ohio. Almost all of the landslides were translational, occurring along the contact between colluvial soils and the underlying bedrock (shales, claystones, mudstones). Six sites were selected in the affected area for a detailed study of the shallow landslides. At each site, a record was made of the stratigraphy, slope geometry, number of landslides, landslide dimensions, hydrologic conditions, and influence of vegetation on landslide distribution. Both colluvial soils and underlying bedrock were sampled for laboratory investigations, which included determination of natural water content, grain size distribution, Atterberg limits, permeability, slake durability, and shear-strength parameters. Data from laboratory tests were used to perform sensitivity and stability analyses with respect to varying slope angles, strength parameters, and thicknesses of saturated colluvial soil. The results of the study indicate that the shallow landslides along Interstate 77 occurred when the colluvial soils reached 90% to 100% saturation, depending upon the slope angles.  相似文献   
988.
The Cascade Lake shear zone occurs on the eastern margin of the Tuolumne Intrusive Suite, Sierra Nevada Batholith, California. Foliation in the zone is NNW trending and subvertical, and lineation is moderately south plunging. Deformation is syn-tectonic with emplacement of the Cathedral Peak granodiorite. A deformation gradient exists toward the NE margin of this pluton, with higher strains and lower temperatures of deformation found near the contact. We compare fabric data collected very densely in this shear zone using several techniques: field fabrics, 3D orientation of K-feldspar megacrysts, and AMS (anisotropy of magnetic susceptibility) analysis. In general, the results from the three different methods are in agreement. Deformation in this shear zone is part of a larger pattern of deformation within the Cathedral Peak granodiorite, as recorded by AMS analysis, and dextral shearing associated within the last stage of plutonism within the Sierra Nevada magmatic arc.  相似文献   
989.
Summary A new, practically applicable method for characterizing the stiffness anisotropy of rocks is presented. The anisotropy of geo-materials is often ignored in engineering applications, with potentially serious ramifications, because of the number of parameters required for characterization. The elastic anisotropy has often been considered to be a function of mathematical symmetry, and the restrictions due to layering, microcracking and granularity of the materials have not been considered in the assessment of the anisotropy. The practicality of the method proposed here is achieved by rationally reducing the number of independent anisotropy parameters, typically 9 for orthotropic anisotropy, to a system of 4 independent parameters through a systematic theoretical and experimental analysis of these structural restrictions. These 4 parameters are shown to be sufficient for describing the anisotropy of some rocks and sands at small strains, and parameter determination by back-analysis is demonstrated to be stable using appropriate measurement systems involving 9 elastic wave velocities even when the directions of anisotropic axes are unknown and the velocity data contains appreciable error.  相似文献   
990.
This paper attempts to determine the impact of former Pb-Zn-Ba mining activities in Slovenian drainage basin on overbank sediments of the Sava river (West Croatia). Among the four studied sequences (S7, S8, S9, S10), the most upstream profile S7 showed the most pronounced impact of ore mining. Mercury was enriched more than 100-fold; Pb and Zn had a strong positive correlation (r > 0.99). Two factor models clearly revealed the Pb-Ba-Hg association in the lower-lying carbonate (CA) population of all four profiles, but only in the overlying silicate (SI) population of profile S7. Factor analysis confirmed this association in the total sediment (90 samples) as well as separately in the CA (33 samples) and SI (57 samples) populations. Based on a comparison with an undisturbed soil profile, the vertical distribution of 137Cs in profile S7 was interpreted to be the combination of caesium deposition caused by a flood in 1964 and by post-depositional redistribution.  相似文献   
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